Articles | Volume 12, issue 1
https://doi.org/10.5194/jsss-12-175-2023
https://doi.org/10.5194/jsss-12-175-2023
Regular research article
 | 
06 Jun 2023
Regular research article |  | 06 Jun 2023

Investigation of the degree of cross-linking of polyethylene and thermosets using absolute optical spectroscopy and Raman microscopy

Florian Bergmann, Norbert Halmen, Claudia Scalfi-Happ, Dominik Reitzle, Alwin Kienle, Linda Mittelberg, Benjamin Baudrit, Thomas Hochrein, and Martin Bastian

Related authors

Single-sided NMR for the measurement of the degree of cross-linking and curing
Norbert Halmen, Christoph Kugler, Eduard Kraus, Benjamin Baudrit, Thomas Hochrein, and Martin Bastian
J. Sens. Sens. Syst., 7, 21–30, https://doi.org/10.5194/jsss-7-21-2018,https://doi.org/10.5194/jsss-7-21-2018, 2018
Short summary
Ultrasound tomography for inline monitoring of plastic melts
Norbert Halmen, Christoph Kugler, Thomas Hochrein, Peter Heidemeyer, and Martin Bastian
J. Sens. Sens. Syst., 6, 9–18, https://doi.org/10.5194/jsss-6-9-2017,https://doi.org/10.5194/jsss-6-9-2017, 2017
Short summary

Related subject area

Sensor principles and phenomena: Optical and infrared sensors
Miniaturized two-chamber photoacoustic CO2 sensor with a wafer-bonded MEMS (micro-electro-mechanical systems) detector
Simon Gaßner, Simon Essing, David Tumpold, Katrin Schmitt, and Jürgen Wöllenstein
J. Sens. Sens. Syst., 13, 219–226, https://doi.org/10.5194/jsss-13-219-2024,https://doi.org/10.5194/jsss-13-219-2024, 2024
Short summary
Concatenated Bragg grating fiber-optic sensors for simultaneous measurement of curvature, temperature, and axial pressure
Sohrab Shojaei Khatouni, Sven Zakowski, Reza Hosseini Vedad, Mustafa Masjedi, Akram Askar, Jan Christian Eli Ewald, and Hoc Khiem Trieu
J. Sens. Sens. Syst., 13, 147–155, https://doi.org/10.5194/jsss-13-147-2024,https://doi.org/10.5194/jsss-13-147-2024, 2024
Short summary
Optical and tactile measurements on SiC sample defects
Jana Grundmann, Bernd Bodermann, Elena Ermilova, Matthias Weise, Andreas Hertwig, Petr Klapetek, Jila Rafighdoost, and Silvania F. Pereira
J. Sens. Sens. Syst., 13, 109–121, https://doi.org/10.5194/jsss-13-109-2024,https://doi.org/10.5194/jsss-13-109-2024, 2024
Short summary
Compact silicon-based attenuated total reflection (ATR) sensor module for liquid analysis
Armin Lambrecht, Carsten Bolwien, Hendrik Fuhr, Gerd Sulz, Annett Isserstedt-Trinke, André Magi, Steffen Biermann, and Jürgen Wöllenstein
J. Sens. Sens. Syst., 12, 123–131, https://doi.org/10.5194/jsss-12-123-2023,https://doi.org/10.5194/jsss-12-123-2023, 2023
Short summary
Real-time active-gas imaging of small gas leaks
Max Bergau, Thomas Strahl, Benjamin Scherer, and Jürgen Wöllenstein
J. Sens. Sens. Syst., 12, 61–68, https://doi.org/10.5194/jsss-12-61-2023,https://doi.org/10.5194/jsss-12-61-2023, 2023
Short summary

Cited articles

Bergmann, F., Foschum, F., Zuber, R., and Kienle, A.: Precise determination of the optical properties of turbid media using an optimized integrating sphere and advanced Monte Carlo simulations. Part 2: Experiments, Appl. Optics, 59, 3216–3226, 2020. a, b, c, d
Case, K . and Zweifel, P. F.: Existence and uniqueness theorems for the neutron transport equation, J. Math. Phys., 4, 1376–1385, 1963. a
DIN: Pipes and fittings made of crosslinked polyethylene (PE-X) – Estimation of the degree of crosslinking by determination of the gel content (ISO 10147:2011), DIN, 2012. a, b
DIN: Plastics – Differential scanning calorimetry (DSC) – Part 5: Determination of characteristic reaction-curve temperatures and times, enthalpy of reaction and degree of conversion (ISO 11357-5:2014), DIN, July 2014. a
DIN: Plastics – Differential scanning calorimetry (DSC) – Part 3: Determination of temperature and enthalpy of melting and crystallization (ISO 11357-3:2018), DIN, July 2018.  a, b
Download
Short summary
In this work, the determination of the degree of cross-linking was investigated using absolute optical measurements with an integrating sphere and Raman spectroscopy. PE-Xc, on the basis of HDPE and UHMWPE and various thermosets, was examined. Laboratory methods (e.g. wet chemical analysis, DSC, and DEA) were used for comparison. A good correlation of the results of the optical methods with those of the laboratory methods could be shown and serves as a basis for further investigations.