Articles | Volume 4, issue 1
https://doi.org/10.5194/jsss-4-53-2015
https://doi.org/10.5194/jsss-4-53-2015
Regular research article
 | 
12 Feb 2015
Regular research article |  | 12 Feb 2015

Alternative strategy for manufacturing of all-solid-state reference electrodes for potentiometry

J. C. B. Fernandes and E. V. Heinke

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Short summary
All-solid-state reference electrodes were developed based on particles of graphite/silver/silver chloride synthesized by electroless deposition of metallic silver and silver chloride on graphite powder. These electrodes were not sensitive to abrasion, redox species, pH and high-pressure saturated steam, and were applied successfully in potentiometric cells to measure pH and potassium ions in a complex matrix by direct potentiometry and L-ascorbic acid by potentiometric titration.