Articles | Volume 6, issue 1
J. Sens. Sens. Syst., 6, 223–236, 2017

Special issue: Sensors and Measurement Systems 2016

J. Sens. Sens. Syst., 6, 223–236, 2017

Regular research article 23 May 2017

Regular research article | 23 May 2017

Simultaneous in situ characterisation of bubble dynamics and a spatially resolved concentration profile: a combined Mach–Zehnder holography and confocal Raman-spectroscopy sensor system

Jajnabalkya Guhathakurta1, Daniela Schurr2, Günter Rinke2, Roland Dittmeyer2, and Sven Simon1 Jajnabalkya Guhathakurta et al.
  • 1Institute for Parallel and Distributed Systems (IPVS), Department of Parallel Systems, Universitätsstr. 38, 70569 Stuttgart, Germany
  • 2Institute for Micro Process Engineering (IMVT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract. For a reaction between a gaseous phase and a liquid phase, the interaction between the hydrodynamic conditions, mass transport and reaction kinetics plays a crucial role with respect to the conversion and selectivity of the process. Within this work, a sensor system was developed to simultaneously characterise the bubble dynamics and the localised concentration measurement around the bubbles. The sensor system is a combination of a digital Mach–Zehnder holography subsystem to measure bubble dynamics and a confocal Raman-spectroscopy subsystem to measure localised concentration. The combined system was used to investigate the chemical absorption of CO2 bubbles in caustic soda in microchannels. The proposed set-up is explained and characterised in detail and the experimental results are presented, illustrating the capability of the sensor system to simultaneously measure the localised concentration of the carbonate ion with a good limit of detection and the 3-D position of the bubble with respect to the spot where the concentration was measured.