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Journal of Sensors and Sensor Systems An open-access peer-reviewed journal
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A commercial solid electrolyte gas sensor of the type "Pt|YSZ|Pt, air" based on yttria-stabilized zirconia for colorimetric oxygen detection was operated in optimized dynamic electrochemical modes. Cyclic voltammetry and square-wave voltammetry were used for the detection of NO and O2 in N2 in the temperature range between 550 and 750 °C. Due to the differences of electrode kinetics of the single components it is possible to detect these redox active gases selectively and quasi-simultaneously.
JSSS | Articles | Volume 9, issue 2
J. Sens. Sens. Syst., 9, 355–362, 2020
https://doi.org/10.5194/jsss-9-355-2020

Special issue: Dresden Sensor Symposium DSS 2019

J. Sens. Sens. Syst., 9, 355–362, 2020
https://doi.org/10.5194/jsss-9-355-2020

Regular research article 29 Oct 2020

Regular research article | 29 Oct 2020

Cyclic and square-wave voltammetry for selective simultaneous NO and O2 gas detection by means of solid electrolyte sensors

Anastasiya Ruchets et al.

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Cited articles

Crocoll, M. and Weisweiler, W.: Kinetische Untersuchungen zur Pt-katalysierten Oxidation von NO: Modellierung und Simulation, Chem. Ing.-Tech., 76, 1490–1494, https://doi.org/10.1002/cite.200403426, 2004. 
Donker, N., Ruchets, A., Schönauer-Kamin, D., Zosel, J., Guth, U., and Moos, R.: Influence of polarization time and polarization current of Pt|YSZ-based NO sensors utilizing the pulsed polarization when applying constant charge, Sensor. Actuat. B-Chem., 290, 28–33, https://doi.org/10.1016/j.snb.2019.03.060, 2019. 
Fischer, S., Pohle, R., Magori, E., Fleischer, M., and Moos, R.: Detection of NO by pulsed polarization of Pt I YSZ, Solid State Ionics, 262, 288–291, https://doi.org/10.1016/j.ssi.2014.01.022, 2014. 
Jaccoud, A., Falgairette, C., Fóti, G., and Comninellis, C.: Charge storage in the O2(g),Pt/YSZ system, Electrochim. Acta, 52, 7927–7935, https://doi.org/10.1016/j.electacta.2007.06.046, 2007. 
Miura, N., Raisen, T., Lu, G., and Yamazoe, N.: Highly selective CO sensor using stabilized zirconia and a couple of oxide electrodes, Sensor. Actuat. B-Chem., 47, 84–91, https://doi.org/10.1016/S0925-4005(98)00053-7, 1998. 

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Short summary
A commercial solid electrolyte gas sensor of the type "Pt|YSZ|Pt, air" based on yttria-stabilized zirconia for colorimetric oxygen detection was operated in optimized dynamic electrochemical modes. Cyclic voltammetry and square-wave voltammetry were used for the detection of NO and O2 in N2 in the temperature range between 550 and 750 °C. Due to the differences of electrode kinetics of the single components it is possible to detect these redox active gases selectively and quasi-simultaneously.
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