Articles | Volume 9, issue 2
https://doi.org/10.5194/jsss-9-383-2020
https://doi.org/10.5194/jsss-9-383-2020
Regular research article
 | 
11 Nov 2020
Regular research article |  | 11 Nov 2020

Glass electrode half-cells for measuring unified pH in ethanol–water mixtures

Agnes Heering, Frank Bastkowski, and Steffen Seitz

Related authors

The density–salinity relation of standard seawater
Hannes Schmidt, Steffen Seitz, Egon Hassel, and Henning Wolf
Ocean Sci., 14, 15–40, https://doi.org/10.5194/os-14-15-2018,https://doi.org/10.5194/os-14-15-2018, 2018
Short summary

Related subject area

Sensor principles and phenomena: Chemical and biochemical sensors
Design of a dual electrochemical quartz crystal microbalance with dissipation monitoring
Rafael Ecker, Nikolaus Doppelhammer, Bernhard Jakoby, and Erwin Konrad Reichel
J. Sens. Sens. Syst., 11, 21–28, https://doi.org/10.5194/jsss-11-21-2022,https://doi.org/10.5194/jsss-11-21-2022, 2022
Short summary
Surface plasmon assisted toxic chemical NO2 gas sensor by Au ∕ ZnO functional thin films
Ravinder Gaur, Himanshu Mohan Padhy, and Manikandan Elayaperumal
J. Sens. Sens. Syst., 10, 163–169, https://doi.org/10.5194/jsss-10-163-2021,https://doi.org/10.5194/jsss-10-163-2021, 2021
Short summary
Studies on porosity in poly(N-isopropylacrylamide) hydrogels for fast-responsive piezoresistive microsensors
Daniela Franke and Gerald Gerlach
J. Sens. Sens. Syst., 10, 93–100, https://doi.org/10.5194/jsss-10-93-2021,https://doi.org/10.5194/jsss-10-93-2021, 2021
Ceramic multilayer technology as a platform for miniaturized sensor arrays for water analysis
Claudia Feller and Uwe Partsch
J. Sens. Sens. Syst., 10, 83–91, https://doi.org/10.5194/jsss-10-83-2021,https://doi.org/10.5194/jsss-10-83-2021, 2021
Short summary
Cyclic and square-wave voltammetry for selective simultaneous NO and O2 gas detection by means of solid electrolyte sensors
Anastasiya Ruchets, Nils Donker, Jens Zosel, Daniela Schönauer-Kamin, Ralf Moos, Ulrich Guth, and Michael Mertig
J. Sens. Sens. Syst., 9, 355–362, https://doi.org/10.5194/jsss-9-355-2020,https://doi.org/10.5194/jsss-9-355-2020, 2020
Short summary

Cited articles

Anon: Liquid junction, IUPAC, Compend. Chem. Terminol., 2nd Edn. (the “Gold Book”), https://doi.org/10.1351/goldbook.L03584, 2019. 
Beliustin, A. A., Pisarevsky, A. M., Lepnev, G. P., Sergeyev, A. S., and Shultz, M. M.: Glass electrodes: a new generation, Sensors Actuat. B, 10, 61–66, https://doi.org/10.1016/0925-4005(92)80012-M, 1992. 
Ermantraut, A., Radtke, V., Gebel, N., Himmel, D., Koslowski, T., and Leito, I.: The ideal ionic liquid salt bridge for direct determination of Gibbs Energies of transfer os single ions, part II: Evaluation of the role of ion solvation and ion mobilities, Angew. Chemie Int. Ed., 57, 2348–2352, https://doi.org/10.1002/anie.201707334, 2018. 
Heering, A.: Dataset for Glass electrode half-cells for measuring unified pH in ethanol-water mixtures [Data set], Journal of Sensors and Sensor Systems, Zenodo, https://doi.org/10.5281/zenodo.4266452, 2020. 
Download
Short summary
The new concept of a unified pH scale can be used to compare acidities of different kinds of solvents and their mixtures. The aim of the work was to investigate the robustness of the measurement method with four commercially available glass electrodes for non-aqueous media in comparison with the rather specific type of cell used so far for this measurement. The measurement results in aqueous mixtures of ethanol show good agreement.