Articles | Volume 12, issue 1
https://doi.org/10.5194/jsss-12-37-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/jsss-12-37-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Resonant photoacoustic cells for laser-based methane detection
Katrin Schmitt
CORRESPONDING AUTHOR
Fraunhofer Institute for Physical Measurement Techniques IPM,
Georges-Koehler-Allee 301, 79110 Freiburg, Germany
University of Freiburg, Institute of Microsystems Engineering,
Laboratory for Gas Sensors, Georges-Koehler-Allee 102, 79110 Freiburg,
Germany
Mara Sendelbach
Fraunhofer Institute for Physical Measurement Techniques IPM,
Georges-Koehler-Allee 301, 79110 Freiburg, Germany
present address: Diotec Semiconductor AG, Kreuzmattenstrasse 4, 79423 Heitersheim, Germany
Christian Weber
Fraunhofer Institute for Physical Measurement Techniques IPM,
Georges-Koehler-Allee 301, 79110 Freiburg, Germany
University of Freiburg, Institute of Microsystems Engineering,
Laboratory for Gas Sensors, Georges-Koehler-Allee 102, 79110 Freiburg,
Germany
Jürgen Wöllenstein
Fraunhofer Institute for Physical Measurement Techniques IPM,
Georges-Koehler-Allee 301, 79110 Freiburg, Germany
University of Freiburg, Institute of Microsystems Engineering,
Laboratory for Gas Sensors, Georges-Koehler-Allee 102, 79110 Freiburg,
Germany
Thomas Strahl
Fraunhofer Institute for Physical Measurement Techniques IPM,
Georges-Koehler-Allee 301, 79110 Freiburg, Germany
University of Freiburg, Institute of Microsystems Engineering,
Laboratory for Gas Sensors, Georges-Koehler-Allee 102, 79110 Freiburg,
Germany
Related authors
Simon Gaßner, Simon Essing, David Tumpold, Katrin Schmitt, and Jürgen Wöllenstein
J. Sens. Sens. Syst., 13, 219–226, https://doi.org/10.5194/jsss-13-219-2024, https://doi.org/10.5194/jsss-13-219-2024, 2024
Short summary
Short summary
This article describes a small prototype sensor designed to sense carbon dioxide (CO2) levels for indoor air quality monitoring. The device uses a photoacoustic detector fabricated using a wafer-bonding process. This allows for high-volume production of the sensors. The prototype presented is small in size and can detect CO2 levels as low as 81 ppm with a response time of 53 s. Our results show suitability for application in indoor air quality control systems.
Sebastian Kindorf, Fabio Gutmann, Christian Weber, Benedikt Bierer, Jürgen Wöllenstein, and Chris Stoeckel
J. Sens. Sens. Syst., 15, 89–97, https://doi.org/10.5194/jsss-15-89-2026, https://doi.org/10.5194/jsss-15-89-2026, 2026
Short summary
Short summary
We present an eight-channel evaluation board for ultrasound sonography and photoacoustic imaging. High frame rates enable averaging, improving signal-to-noise ratio. The board integrates a programmable preamplifier and an analog front-end with 12-bit analog-to-digital conversion, with data transmitted via Ethernet for PC evaluation. Gain distribution and its effect on signal-to-noise ratio in a multichannel photoacoustic receive chain are quantitatively characterized at 540 frames per second.
Simon Gaßner, Simon Essing, David Tumpold, Katrin Schmitt, and Jürgen Wöllenstein
J. Sens. Sens. Syst., 13, 219–226, https://doi.org/10.5194/jsss-13-219-2024, https://doi.org/10.5194/jsss-13-219-2024, 2024
Short summary
Short summary
This article describes a small prototype sensor designed to sense carbon dioxide (CO2) levels for indoor air quality monitoring. The device uses a photoacoustic detector fabricated using a wafer-bonding process. This allows for high-volume production of the sensors. The prototype presented is small in size and can detect CO2 levels as low as 81 ppm with a response time of 53 s. Our results show suitability for application in indoor air quality control systems.
Armin Lambrecht, Carsten Bolwien, Hendrik Fuhr, Gerd Sulz, Annett Isserstedt-Trinke, André Magi, Steffen Biermann, and Jürgen Wöllenstein
J. Sens. Sens. Syst., 12, 123–131, https://doi.org/10.5194/jsss-12-123-2023, https://doi.org/10.5194/jsss-12-123-2023, 2023
Short summary
Short summary
Infrared spectroscopy is great for determining the composition of liquids. Combined with attenuated total reflection (ATR), one can just put the sample on the sensitive surface. We made a compact device with a diamond-coated silicon ATR crystal to protect the surface against aggressive fluids. Silicon crystal, light source and detector are hermetically sealed in a housing. Our tests show that the diamond coating enhanced the sensitivity compared to uncoated ATR elements as predicted by theory.
Max Bergau, Thomas Strahl, Benjamin Scherer, and Jürgen Wöllenstein
J. Sens. Sens. Syst., 12, 61–68, https://doi.org/10.5194/jsss-12-61-2023, https://doi.org/10.5194/jsss-12-61-2023, 2023
Short summary
Short summary
Imaging of greenhouse gases is of great interest due to global warming. A spectroscopic method, using an active illumination of the scene, is presented. It allows for imaging and concentration measurements of much smaller gas plumes and leaks than current state-of-the-art gas cameras (optical gas imaging cameras). A real-time camera is realized and validated using known methane concentrations.
Benedikt Bierer, Dario Grgić, Olena Yurchenko, Laura Engel, Hans-Fridtjof Pernau, Martin Jägle, Leonhard Reindl, and Jürgen Wöllenstein
J. Sens. Sens. Syst., 10, 185–191, https://doi.org/10.5194/jsss-10-185-2021, https://doi.org/10.5194/jsss-10-185-2021, 2021
Short summary
Short summary
Detection of flammable gases is necessary to avoid explosive atmospheres. Commercial pellistors require an operation temperature above 450 °C for the detection of methane. We present a novel wireless low-power catalytic gas sensor system based on non-precious metal catalyst for the detection of methane and propane operated at 350 °C. The combination of a MEMS-based sensor with a low-power radio system provides the opportunity to monitor complex infrastructures without using a power grid.
Cited articles
Baumann, B., Kost, B., Wolff, M., and Groninga, H.: Modeling and numerical
investigation of photoacoustic resonators,
INTECH Open Access Publisher, 17–38. doi10.5772/6798, 2008.
Baumann, B., Kost, B., Groninga, H., and Wolff, M.: Eigenmode analysis of
photoacoustic sensors via finite element method. Rev. Sci. Instrum., 77, 044901,
https://doi.org/10.1063/1.2186808, 2006.
Bozóki, Z., Pogány, A., and Szabó, G.: Photoacoustic Instruments
for Practical Applications: Present, Potentials, and Future Challenges,
Appl. Spectrosc. Rev., 46, 1–37,
https://doi.org/10.1080/05704928.2010.520178, 2011.
Dong, L., Tittel, F. K., Li, C., Sanchez, N. P., Wu, H., Zheng, C., Yu, Y.,
Sampaolo, A., and Griffin, R. J.: Compact TDLAS based sensor design using
interband cascade lasers for mid-IR trace gas sensing, Opt. Expr., 24,
A528–A535, https://doi.org/10.1364/OE.24.00A528, 2016.
Dumitras, D. C., Dutu, D. C., Matei, C., Magureau, A. M., Petrus, M., and
Popa, C.: Laser photoacoustic spectroscopy: principles, instrumentation, and
characterization, J. Optoelectron. Adv. Mat., 9, 12, 3655–3701,
WOS:000251768700001, 2007.
Elia, A., Luagarà, P. M., Franco, C. D., and Spagnolo, V.: Photoacoustic
Techniques for Trace Gas Sensing Based on Semiconductor Laser Sources,
Sensors, 9, 12, 9616–9628, https://doi.org/10.3390/s91209616, 2009.
El-Safoury, M., Weber, C., Kiesewetter, O., Hespos, Y., Eberhardt, A., Schmitt, K., and Wöllenstein, J.: Miniaturized photoacoustic detection of organofluorine-based refrigerants, J. Sens. Sens. Syst., 9, 89–97, https://doi.org/10.5194/jsss-9-89-2020, 2020.
Feng, L., Palmer, P. I., Zhu, S., Parker, R. J., and Liu, Y.: Tropical
methane emissions explain large fraction of recent changes in global
atmospheric methane growth rate, Nat. Commun., 13, 1–8,
https://doi.org/10.1038/s41467-022-28989-z, 2022.
Gassner, S., Schaller, R., Eberl, M., von Koblinski, C., Essing, S.,
Ghaderi, M., Schmitt, K., and Wöllenstein, J.: Anodically Bonded
Photoacoustic Transducer: An Approach towards Wafer-Level Optical Gas
Sensors, Sensors, 22, 685, https://doi.org/10.3390/s22020685, 2022.
IEA: Methane Tracker 2021, IEA, Paris, https://www.iea.org/reports/methane-tracker-2021 (last access: 5 December 2022), 2021.
Jorgenson, A. K.: Global warming and the neglected greenhouse gas: A
cross-national study of the social causes of methane emissions intensity,
1995, Soc. Forces, 84, 1779–1798,
https://doi.org/10.1353/sof.2006.0050, 2006.
Lackner, M.: Tunable diode laser absorption spectroscopy (TDLAS) in the
process industries–a review. Rev. Chem. Eng., 23, 65–147,
https://doi.org/10.1515/REVCE.2007.23.2.65, 2007.
Li, J., Chen, W., and Yu, B.: Recent progress on infrared photoacoustic
spectroscopy techniques, Appl. Spectrosc. Rev., 46, 440–471,
https://doi.org/10.1080/05704928.2011.570835, 2011.
Miklós, A., Hess, P., and Bozóki, Z.: Application of acoustic
resonators in photoacoustic trace gas analysis and metrology, Rev. Sci.
Instrum., 72, 1937–1955, https://doi.org/10.1063/1.1353198, 2001.
Morse, P. M. and Ingard, K. U.: Theoretical acoustics, Princeton
University Press, Princeton, New Jersey, ISBN 0-691-08425-4, 1986.
Petersen, A. K., Warneke, T., Frankenberg, C., Bergamaschi, P., Gerbig, C., Notholt, J., Buchwitz, M., Schneising, O., and Schrems, O.: First ground-based FTIR observations of methane in the inner tropics over several years, Atmos. Chem. Phys., 10, 7231–7239, https://doi.org/10.5194/acp-10-7231-2010, 2010.
Ripperger, S. and Germerdonk, R.: Quantitative gas analysis by infrared
spectroscopy, Chem.-Ing.-Tech., 55, 58–561, 1983.
Thomas, S. and Haider, N. S.: Instruments for methane gas detection, J. Eng.
Res. Appl., 4, 137–143, 2014.
Schilt, S., Besson, J.-P., and Thévenaz, L.: Near-infrared laser
photoacoustic detection of methane: the impact of molecular relaxation,
Appl. Phys. B, 82, 319–328, https://doi.org/10.1007/s00340-005-2076-y, 2006.
Wolff, M., Groninga, H. G., Baumann, B., Kost, B., and Harde, H.: Resonance
Investigations using PAS and FEM, Acta Acust., 91, 99,
http://hdl.handle.net/20.500.12738/2208 (last access: 5 December 2022), 2005.
Werle, P., Mücke, R., and Slemr, F.: The Limits of Signal Averaging in
Atmospheric Trace-Gas Monitoring by Tunable Diode-Laser Absorption
Spectroscopy (TDLAS), Appl. Phys. B, 57, 131–139,
https://doi.org/10.1007/BF00425997, 1993
Wittstock, V., Scholz, L., Bierer, B., Perez, A. O., Wöllenstein, J.,
and Palzer, S.: Design of a LED-based sensor for monitoring the lower
explosion limit of methane, Sens. Actuators B, 247, 930–939,
https://doi.org/10.1016/j.snb.2017.03.086, 2017.
Wolff, M., Rhein, S., Bruhns, H., Nähle, L., Fischer, M., and Koeth, J.:
Photoacoustic methane detection using a novel DFB-type diode laser at 3.3
μm. Sens, Actuators B: Chemical, 187, 574–577,
https://doi.org/10.1016/j.snb.2013.04.084, 2013.
Ye, W., Tu, Z., Xiao, X., Simeone, A., Yan, J., Wu, T., Wu, F., Zheng, C.,
and Tittel, F. K.: A NDIR mid-infrared methane sensor with a compact
pentahedron gas-cell. Sensors, 20, 5461,
https://doi.org/10.3390/s20195461, 2020.
Zhao, Z. J., Liu, D. X., Zhang, J. L., Wang, Z. B., Li, X., and Tian, E. M.:
Design of non-dispersed infrared (NDIR) methane gas sensor, Spectrosc. Spec.
Anal., 31, 570–573,
https://doi.org/10.3964/j.issn.1000-0593(2011)02-0570-04, 2011.
Short summary
We present a photoacoustic sensor enabling fast, inexpensive, and highly sensitive methane detection in environmental monitoring applications. Six different T-cell designs were both theoretically and experimentally investigated. The aim was to understand the photoacoustic signal generation and resonances in relation to the different cell geometries, and determine the long-term stability and the detection limits for methane. These were below the methane background concentration in air of 1.8 ppm.
We present a photoacoustic sensor enabling fast, inexpensive, and highly sensitive methane...
Special issue